OBB Railjet should be a quick 4 hour high speed train. If you’re set on the timing, is not too expensive for economy class. I did Praha-Wien a few years ago and booked closer in, to the point where the First Class (and then even further Business Class, which is above F) made sense to splurge on, and we got a bit more space.
The earlier you book, the cheaper it generally is. Not sure how far out you can book. There are also private rail services in addition to state services. I think it’s Student Agency, they’re based in Prague. They should show up on the general rail schedule services like RailNinja or RailEurope.
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